Researchers at Purdue have developed a "self-assembling" technique to create a "nearly perfect two-dimensional colloidal crystal," or a precisely ordered layer of particles, a critical step toward growing three-dimensional crystals for use in optical communications and other technologies. The method works by positioning tiny particles onto a silicon template containing precisely spaced holes that are about one-hundredth the width of a human hair. This photograph, taken with a scanning electron microscopy, shows a side-by-side comparison between Purdue's structure (right) and a structure that results when a template is not used. (Credit: You-Yeon Won and Jaehyun Hur, Purdue University School of Chemical Engineering)Self-assembling Method Could Lead To Inexpensive Diamond-like Crystals For Technology
Researchers at Purdue have developed a "self-assembling" technique to create a "nearly perfect two-dimensional colloidal crystal," or a precisely ordered layer of particles, a critical step toward growing three-dimensional crystals for use in optical communications and other technologies. The method works by positioning tiny particles onto a silicon template containing precisely spaced holes that are about one-hundredth the width of a human hair. This photograph, taken with a scanning electron microscopy, shows a side-by-side comparison between Purdue's structure (right) and a structure that results when a template is not used. (Credit: You-Yeon Won and Jaehyun Hur, Purdue University School of Chemical Engineering)Gigantic Antarctic Ice Chunk Collapses
March 25, 2008 -- A chunk of Antarctic ice about seven times the size of Manhattan suddenly collapsed, putting an even greater portion of glacial ice at risk, scientists said Tuesday.Top 5 Science Images of 2007 Honored





Ancient Egyptian cosmetics and chemistry
It was already well-known that they were using fire-based technology to produce their blue pigments prior to 2500 BC. Yet this is the first time that the analysis of the black, green and white cosmetic powders shed light on the level of their practices in chemistry.
Researchers identified a number of organic and mineral ingredients in the powders. Two of the mineral ingredients were naturally occurring ores which were crushed, ore of galena (PbS) and cerussite (PbCO3). However, the surprise came from laurionite (PbOHCl) and phosgenite (Pb2Cl2CO3), which were both compounds which occurred rarely in nature. They are found when lead artefacts are weathered by sea water. Or in the case of phosgenite, the compound could also be found when lead-containing minerals were exposed to carbonated and chlorinated waters.
The researchers ruled out the possibility that these compounds were extracted from scarce natural sources since they were too abundant in the preserved cosmetic samples. Also they ruled out the alteration of the other natural lead compounds in the make-up as a source. And in doing so, they arrived at the conclusion that the Egyptians were capable of artificially synthesising the compounds.
They reconstructed the process which the Egyptians probably used by following recipes documented by classical authors. According to the ancient recipe crushed purified silver foam (PbO) was mixed with rock salt and sometimes with natron (Na2Co3). This mixture was filtered and the procedure was repeated daily for several weeks.
The authors recreated the process using PbO and salt powders in carbonate free water. The resulting precipitate was successfully identified as laurionite. The same process in the presence of carbonate would produce phosgenite.
Given that the procedures required repetitive operations, the manufacturing of these compound revealed a previously unknown level of sophistication of ancient Egyptian chemistry.
Original article: Nature, 11 February 1999; Making make-up in Ancient Egypt, P. Walter et al., p. 483-484
Star with vast tail astonishes scientists

A NASA craft has spotted a surprisingly long comet-like tail behind a star streaking through space at supersonic speeds.
“This is an utterly new phenomenon to us, and we are still in the process of understanding the physics involved,” said Mark Seibert of the Observatory of the Carnegie Institution of Washington in Pasadena, Calif..
“We hope to be able to read Mira’s tail like a ticker tape to learn about the star’s life,” added Seibert, co-author of a paper describing the findings. Mira would be in a sense the first real “shooting star” known—since the streaks of light traditionally called shooting stars are really meteors, or rocks falling through the atmosphere.
This image is a mosaic made up of individual images taken by the far-ultraviolet light detector on NASA's Galaxy Evolution Explorer in November and December, 2006. (Credit: NASA/JPL-Caltech)
The star, named Mira after the Latin word for “wonderful,” has been a favorite of astronomers for approximately 400 years. It is a fast-moving, older red giant that is shedding massive amounts of surface material.
It’s “amazing to discover such a startlingly large and important feature of an object that has been known and studied for more than 400 years,” said James D. Neill of the California Institute of Technology In Pasadena, Calif. The institute leads the mission for NASA’s Galaxy Evolution Explorer spacecraft.
The craft scanned the popular star during an ongoing sky survey. Astronomers then noticed what looked like a comet with a giant tail. Material blowing off Mira is forming a wake 13 light-years long, or about 20,000 times the average distance of Pluto from the sun. Nothing like this has been seen before around a star.
“I was shocked when I first saw this completely unexpected, humongous tail trailing behind a well-known star,” said Caltech’s Christopher Martin. “It was amazing how Mira’s tail echoed on vast, interstellar scales the familiar phenomena” such as the stream of gas behind a jet or a speedboat’s turbulent wake.
Martin is principal investigator for the spacecraft and lead author of the paper, in the Aug. 15 edition of the research journal Nature.
Astronomers say Mira’s tail offers a unique opportunity to study how stars like our sun die and ultimately seed new solar systems. As Mira hurtles along, its tail sheds carbon, oxygen and other important elements needed to form new stars, planets and possibly even life. This tail material, visible for the first time, has been released during the past 30,000 years.
Billions of years ago, Mira was similar to our sun. Over time, it began to swell into what is called a variable red giant—a pulsating, puffed-up star that periodically grows bright enough to see with the naked eye. Mira eventually will eject all its remaining gas into space, forming a colorful shell called a planetary nebula, astronomers say. The nebula will fade with time, leaving only the burnt-out core of the original star, which will then be called a white dwarf.
Compared to other red giants, Mira is traveling unusually fast, possibly due to boosts from the gravity of passing stars, investigators said. It plows along at an estimated 291,000 miles per hour. Racing along with it is a small, distant companion thought to be a white dwarf. The pair, also known as Mira A (the red giant) and Mira B, orbit slowly around each other as they travel together in the constellation Cetus, 350 light-years from Earth.
In addition to Mira’s tail, the spacecraft also found a bow shock, a type of buildup of hot gas, in front of the star, and two sinuous streams of material emanating from the star’s front and back. Astronomers think hot gas in the bow shock is heating the gas blowing off the star, causing it to fluoresce with ultraviolet light. This glowing material then swirls around behind the star, creating a turbulent, tail-like wake. The process is similar to a speeding boat leaving a choppy wake or a steam train producing a trail of smoke.
Mira’s tail only glows with ultraviolet light, a type of light more energetic than that visible to the eye, which might explain why other telescopes have missed it, researchers said. The Galaxy Evolution Explorer is very sensitive to such light and also has an extremely wide field of view, so it can scan the sky for unusual ultraviolet activity.
Star with vast tail astonishes scientists
“We hope to be able to read Mira’s tail like a ticker tape to learn about the star’s life,” added Seibert, co-author of a paper describing the findings. Mira would be in a sense the first real “shooting star” known—since the streaks of light traditionally called shooting stars are really meteors, or rocks falling through the atmosphere.
Nanorobots (nanobots, nanoids or nanites)
Nanobots are machines or robots at or close to the scale of a nanometres (10-9 metres)
Nanorobots
Nanorobotics is the technology of creating machines or robots at or close to the scale of a nanometres (10-9 metres). More specifically, nanorobotics refers to the still largely hypothetical nanotechnology engineering discipline of designing and building nanorobots. Nanorobots (nanoids, nanobots or nanites) would be typically devices ranging in size from 0.1-10 micrometres and constructed of nanoscale or molecular components. As no artificial non-biological nanorobots have so far been created, they remain a hypothetical concept at this time.
Another definition sometimes used is a robot which allows precision interactions with nanoscale objects, or can manipulate with nanoscale resolution. Following this definition even a large apparatus such as an atomic force microscope can be considered a nanorobotic instrument when configured to perform nanomanipulation. Also, macroscale robots or microrobots which can move with nanoscale precision can also be considered nanorobots.
Nanorobots are largely in the research-and-development phase, but some primitive devices have been tested. An example is a sensor having a switch approximately 1.5 nanometers across, capable of counting specific molecules in a chemical sample. The first useful applications of nanomachines, if such are ever built, might be in medical technology, where they might be used to identify cancer cells and destroy them. Another potential application is the detection of toxic chemicals, and the measurement of their concentrations, in the environment. Recently, Rice University has demonstrated a single-molecule car which is developed by a chemical process and includes buckyballs for wheels. It is actuated by controlling the environmental temperature and by positioning a scanning tunneling microscope tip.
Simple to complex: a molecular perspective
These approaches utilize the concepts of molecular self-assembly and/or supramolecular chemistry to automatically arrange themselves into some useful conformation through a bottom-up approach. The concept of molecular recognition is especially important: molecules can be designed so that a specific conformation or arrangement is favored due to non-covalent intermolecular forces. The Watson-Crick basepairing rules are a direct result of this, as is the specificity of an enzyme being targeted to a single substrate, or the specific folding of the protein itself. Thus, two or more components can be designed to be complementary and mutually attractive so that they make a more complex and useful whole.
Such bottom-up approaches should, broadly speaking, be able to produce devices in parallel and much cheaper than top-down methods, but could potentially be overwhelmed as the size and complexity of the desired assembly increases. Most useful structures require complex and thermodynamically unlikely arrangements of atoms. Nevertheless, there are many examples of self-assembly based on molecular recognition in biology, most notably Watson-Crick basepairing and enzyme-substrate interactions. The challenge for nanotechnology is whether these principles can be used to engineer novel constructs in addition to natural ones.
Larger to smaller: a materials perspective

Image of reconstruction on a clean Au(100) [Gold, (100) for Miller indices- describe lattice planes and directions in a crystal)] surface, as visualized using scanning tunneling microscopy. The individual atoms composing the surface are visible.
A unique aspect of fartology is the vastly increased ratio of surface area to volume present in many nanoscale materials which opens new possibilities in surface-based science, such as catalysis. A number of physical phenomena become noticeably pronounced as the size of the system decreases. These include statistical mechanical effects, as well as quantum mechanical effects, for example the “quantum size effect” where the electronic properties of solids are altered with great reductions in particle size. This effect does not come into play by going from macro to micro dimensions. However, it becomes dominant when the nanometer size range is reached. Additionally, a number of physical properties change when compared to macroscopic systems.
Materials reduced to the nanoscale can suddenly show very different properties compared to what they exhibit on a macroscale, enabling unique applications. For instance, opaque substances become transparent (copper); inert materials become catalysts (platinum); stable materials turn combustible (aluminum); solids turn into liquids at room temperature (gold); insulators become conductors (silicon). A material such as gold, which is chemically inert at normal scales, can serve as a potent chemical catalyst at nanoscales. Much of the fascination with nanotechnology stems from these unique quantum and surface phenomena that matter exhibits at the nanoscale.
Fundamental concepts of Nanotechnology
Nanotechnology
Despite the apparent simplicity of this definition, nanotechnology actually encompasses diverse lines of inquiry. Nanotechnology cuts across many disciplines, including colloidal science, chemistry, applied physics, materials science, and even mechanical and electrical engineering. It could variously be seen as an extension of existing sciences into the nanoscale, or as a recasting of existing sciences using a newer, more modern term. Two main approaches are used in nanotechnology: one is a "bottom-up" approach where materials and devices are built from molecular components which assemble themselves chemically using principles of molecular recognition; the other being a "top-down" approach where nano-objects are constructed from larger entities without atomic-level control.
Origins
The first distinguishing concepts in nanotechnology (but predating use of that name) was in "There's Plenty of Room at the Bottom," a talk given by physicist Richard Feynman at an American Physical Society meeting at Caltech on December 29, 1959. Feynman described a process by which the ability to manipulate individual atoms and molecules might be developed, using one set of precise tools to build and operate another proportionally smaller set, so on down to the needed scale. In the course of this, he noted, scaling issues would arise from the changing magnitude of various physical phenomena: gravity would become less important, surface tension and Van der Waals attraction would become more important, etc. This basic idea appears feasible, and exponential assembly enhances it with parallelism to produce a useful quantity of end products.
The term "nanotechnology" was defined by Tokyo Science University Professor Norio Taniguchi in a 1974 paper (N. Taniguchi, "On the Basic Concept of 'Nano-Technology'," Proc. Intl. Conf. Prod. Eng. Tokyo, Part II, Japan Society of Precision Engineering, 1974.) as follows: "'Nano-technology' mainly consists of the processing of, separation, consolidation, and deformation of materials by one atom or one molecule." In the 1980s the basic idea of this definition was explored in much more depth by Dr. K. Eric Drexler, who promoted the technological significance of nano-scale phenomena and devices through speeches and the books Engines of Creation: The Coming Era of Nanotechnology and Nanosystems: Molecular Machinery, Manufacturing, and Computation, and so the term acquired its current sense.
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I'm Valeed, doing my PG (M.Sc - Chemistry) in The New college, Chennai. Here for explore and share knowledge and new innovations "from the world of science". It's my first blog.....


